| Gi Group Monza - Diatec Trentino | 3 - 2 | 23-25 25-18 27-25 17-25 15-8 |
| Kioene Padova - Azimut Modena | 1 - 3 | 21-25 26-24 24-26 23-25 |
| Calzedonia Verona - Wixo LPR Piacenza | 3 - 2 | 22-25 16-25 31-29 25-23 15-13 |
| Biosì Indexa Sora - Tonno Callipo Calabria Vibo Valentia | 3 - 1 | 25-19 25-21 22-25 26-24 |
| Sir Safety Conad Perugia - Bunge Ravenna | 3 - 0 | 25-15 25-14 25-19 |
| Revivre Milano - Taiwan Excellence Latina | 2 - 3 | 30-32 18-25 25-16 25-22 10-15 |
| Cucine Lube Civitanova - BCC Castellana Grotte | 3 - 0 | 25-22 25-16 25-12 |